They're great products! I have used both!
I use swarm commander when capturing swarms or encouraging bees to stay in their new box after a cut out.
Honey-b-gone is great for bee removals when they're in a difficult to reach location and you want to encourage them out.. a few squirts gets them moving! I have also used it with a vapour board to quickly clear out a honey super for extraction!
The Bunyip Beekeeper